Douglas Pedersen’s abstract accepted to 240th ECS Meeting

Douglas Pedersen will be presenting his research “Life Cycle Assessment of LiCoO2/Graphite Batteries with Cooling Using Dualfoil Simulations and Simulink” as an oral presentation at the 240th ECS meeting! The presentation will be part of the Z04: Electrochemical Recovery, Recycling, and Sustainability of Critical and Value Added Materials symposium. The 240th ECS meeting will be held online in October.

 

Congrats Douglas!

Misha Bekeris publishes in Physica Status Solidi-Rapid Research Letters

Undergraduate researcher Misha Bekeris is the first-author on the newly accepted publication in PSS-RRL, “Rapid Quantification of Nanosphere Lithography Packing Defects Using Scanning Electron Microscopy Edge Effects”. The paper is available for download at: https://doi.org/10.1002/pssr.202000328

Congratulations Misha!

Abstract

Graphical abstract

Nanosphere lithography (NSL) is a bottom‐up, self‐assembly approach that enables rapid, low‐cost patterning of nanoscale features. The practical application and scalability of NSL relies on the ability to achieve defect‐free nanosphere self‐assembly over large substrate areas. Self‐assembly methods for single‐layer nanosphere templates are typically evaluated using scanning electron microscopy (SEM) imaging, with literature reports focusing on maximum area of continuous nanosphere coverage. An alternative performance metric—namely, the percentage of nanospheres exhibiting perfect hexagonal close‐packing (%HCP)—is uniquely critical to NSL precision and repeatability. To enhance current methods of evaluating nanosphere self‐assembly, this work presents an SEM image analysis approach for rapidly quantifying packing defects in single‐layer nanospheres to determine %HCP. The method uses variations in SEM edge effect brightness to distinguish spheres with perfect packing from those in defect configurations or along edges. Comparison of image analysis program results with manual counting of nanospheres indicates that the program has a high degree of accuracy, with a mean error on the %HCP metric of +8.6% (absolute error). The results suggest that the present strategy offers a promising pathway to rapid evaluation of nanosphere self‐assembly for high‐precision NSL applications such as surface‐enhanced Raman scattering, photovoltaic cells, and nanogap electrodes.

 

February 2020: Warren receives NSF CAREER Award

Department of Mechanical Engineering Assistant Professor Roseanne Warren has been awarded a National Science Foundation Faculty Early Career Development Program (CAREER) award. The CAREER program is one of NSF’s most prestigious award programs, with awards of up to $500,000 over 5 years in support of early-career faculty with potential to serve as academic role models in research and education. The research grant, entitled “CAREER: Roll-to-Roll Fabrication of Porous Materials Using Nanobubble Templates,” will explore new methods of fabricating templated porous materials that are compatible with high-throughput, scalable manufacturing protocols, including roll-to-roll fabrication.

For more information, visit:

https://www.mech.utah.edu/warren-receives-2020-nsf-career-award/

https://www.nsf.gov/awardsearch/showAward?AWD_ID=1943907

September 2019: Lab-on-a-Chip cover article published

Abdullah Alsharhan, Ruben Acevedo, Roseanne Warren, and Ryan Sochol’s recent article, “3D microfluidics via cyclic olefin polymer-based in situ direct laser writing” has been featured on the front cover of the September 7, 2019 issue of Lab on a Chip. The article explores a new method of printing three-dimensional nanostructured components directly inside of enclosed microchannels using cyclic olefin polymer (COP). Demonstrated 3D printing results show that COP-based in-situ direct laser writing offers a promising pathway to wide-ranging fluidic applications that demand significant architectural versatility at submicron scales with invariable sealing integrity, such as for biomimetic organ-on-a-chip systems and integrated microfluidic circuits.

The research is supported by NSF Award numbers 1761395 and 1761273.

Alsharhan et al – 3D microfluidics via cyclic olefin polymer-based in situ direct laser writing

LOC cover

August 2019: PI Warren receives new NSF funding

PI Warren and the Advanced Energy Innovations Lab, in collaboration with Prof. Shad Roundy, has received a research funding award from the National Science Foundation to study new method for direct conversion of thermal energy to stored electrochemical energy. The award will support the training of two graduate student researchers, and provide summer research internship opportunities for local high school students.
Full details are available on the NSF award page.

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February 2019: Nolan Ingersoll et al. publish in Electrochimica Acta

Congrats to Nolan Ingersoll, Zahra Karimi, Dhruv Patel, and Robert Underwood for their recently published article in Electrochemica Acta!

Nolan Ingersoll, Zahra Karimi, Dhruv Patel, Robert Underwood, and Roseanne Warren, “Metal Organic Framework-Derived Carbon Structures for Sodium-Ion Battery Anodes,” Electrochimica Acta, Vol. 297, pp. 129-136, 2019

Abstract:

Metal organic framework-derived carbons (MOFDCs) have great potential as electrochemical energy storage materials due to their large surface areas and highly tunable pore structures. In this work, two MOFDCs are tested as sodium-ion battery anode materials and their charge storage mechanisms compared. MOF5 (Zn4O(1,4-benzodicarboxylate)3) and ZIF8 (Zn(2-methylimidazole)2) were used as sacrificial templates and pyrolyzed to yield highly porous, structurally-robust carbons with high surface areas (MOF5DC and ZIF8DC). Undoped ZIF8DC was tested for the first time as a sodium-ion battery anode to enable comparison of MOFDC charge storage mechanisms based solely on carbon structure. Half-cell discharge tests at C/2 attain capacity values of 227 and 107 mAh/g for MOF5DC and undoped ZIF8DC, respectively. Cycling stability testing confirms the structural robustness of the MOFDC materials, with the anodes retaining between 84-89% capacity over 66 cycles. Discharge profiles for both materials indicate that the primary storage mechanism of MOF5DC and ZIF8DC anodes is adsorption at defect sites. A comparison of half-cell discharge, cycling rate, and electrochemical impedance spectroscopy measurements suggests that MOF5DC also demonstrates some nanopore filling mechanisms. A comparison of Na+ion diffusion coefficients for MOF5DC and ZIF8DC indicates that an MOF structure with increased pore size may improve capacity and rate performance of MOFDCs as anode materials for sodium-ion battery cell applications.

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